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Posts Tagged ‘non-equilibrium’

Monolithic 3D processing using non-equilibrium RTP

Friday, April 17th, 2015


By Ed Korczynski, Senior Technical Editor, Solid State Technology

Slightly more than one year after Qualcomm Technologies announced that it was assessing CEA-Leti’s monolithic 3D (M3D) transistor stacking technology, Qualcomm has now announced that M3D will be used instead of through-silicon vias (TSV) in the company’s next generation of cellphone handset chips. Since Qualcomm had also been a leading industrial proponent of TSV over the last few years while participating in the imec R&D consortium, this endorsement of M3D is particularly relevant.

Leti’s approach to 3D stacking of transistors starts with a conventionally built and locally-interconnected bottom layer of transistors, which are then covered with a top layer of transistors built using relatively low-temperature processes branded as “CoolCube.” Figure 1 shows a simplified cross-sectional schematic of a CoolCube stack of transistors and interconnects. CoolCube M3D does not transfer a layer of built devices as in the approach using TSV, but instead transfers just a nm-thin layer of homogenous semiconducting material for subsequent device processing.

Fig. 1: Simplified cross-sectional rendering of Monolithic 3D (M3D) transistor stacks, with critical process integration challenges indicated. (Source: CEA-Leti)

The reason that completed transistors are not transferred in the first place is because of intrinsic alignment issues, which are eliminated when transistors are instead fabricated on the same wafer. “We have lots of data to prove that alignment precision is as good as can be seen in 2D lithography, typically 3nm,” explained Maud Vinet, Leti’s advanced CMOS laboratory manager in an exclusive interview with SST.

As discussed in a blog post online at Semiconductor Manufacturing and Design ( last year by Leti researchers, the M3D approach consists of sequentially processing:

  • processing a bottom MOS transistor layer with local interconnects,
  • bonding a wafer substrate to the bottom transistor layer,
  • chemical-mechanical planarization (CMP) and SPE of the top layer,
  • processing the top device layer,
  • forming metal vias between the two device layers as interconnects, and
  • standard copper/low-k multi-level interconnect formation.

To transfer a layer of silicon for the top layer of transistors, a cleave-layer is needed within the bulk silicon or else time and money would be wasted in grinding away >95% of the silicon bulk from the backside. For CMOS:CMOS M3D thin silicon-on-insulator (SOI) is the transferred top layer, a logical extension of work done by Leti for decades. The heavy dose ion-implantation that creates the cleave-layer leaves defects in crystalline silicon which require excessively high temperatures to anneal away. Leti’s trick to overcome this thermal-budget issue is to use pre-amorphizing implants (PAI) to completely dis-order the silicon before transfer and then solid-phase epitaxy (SPE) post-transfer to grow device-grade single-crystal silicon at ~500°C.

Since neither aluminum nor copper interconnects can withstand this temperature range, the interconnects for the bottom layer of transistors need to be tungsten wires with the highest melting point of any metal but somewhat worse electrical resistance (R). Protection for the lower wires cannot use low-k dielectrics, but must use relatively higher capacitance (C) oxides. However, the increased RC delay in the lower interconnects is more than offset by the orders-of-magnitude reduction in interconnect lengths due to vertical stacking.

M3D Roadmaps

Leti shows data that M3D transistor stacking can provide immediate benefit to industry by combining two 28nm-node CMOS layers instead of trying to design and manufacture a single 14nm-node CMOS layer:  area gain 55%, performance gain 23%, and power gain 12%. With cost/transistor now expected to increase with sequential nodes, M3D thus provides a way to reduce cost and risk when developing new ICs.

For the industry to use M3D, there are some unique new unit-processes that will need to ramp into high-volume manufacturing (HVM) to ensure profitable line yield. As presented by C. Fenouillet-Beranger et al. from Leti and ST (paper 27.5) at IEDM2014 in San Francisco, “New Insights on Bottom Layer Thermal Stability and Laser Annealing Promises for High Performance 3D Monolithic Integration,” due to stability improvement in bottom transistors found through the use of doping nickel-silicide with a noble metal such as platinum, the top MOSFET processing temperature could be relaxed up to 500°C. Laser RTP annealing then allows for the activation of top MOSFETs junctions, which have been characterized morphologically and electrically as promising for high performance ICs.

Figure 2 shows the new unit-processes at <=500°C that need to be developed for top transistor formation:

*   Gate-oxide formation,

*   Dopant activation,

*   Epitaxy, and

*   Spacer deposition.

Fig. 2: Thermal processing ranges for process modules need to be below ~500°C for the top devices in M3D stacks to prevent degradation of the bottom layer. (Source: CEA-Leti)

After the above unit-processes have been integrated into high-yielding process modules for CMOS:CMOS stacking, heterogeneous integration of different types of devices are on the roadmap for M3D. Leti has already shown proof-of-concept for processes that integrate new IC functionalities into future M3D stacks:

1)       CMOS:CMOS,

2)       PMOS:NMOS,

3)       III-V:Ge, and

4)       MEMS/NEMS:CMOS.

Thomas Ernst, senior scientist, Electron Nanodevice Architectures, Leti, commented to SST, “Any application that will need a ‘pixelated’ device architecture would likely use M3D. In addition, this approach will work well for integrating new channel materials such as III-V’s and germanium, and any materials that can be deposited at relatively low temperatures such as the active layers in gas-sensors or resistive-memory cells.”

Non-Equilibrium Thermal Processing

Though the use of an oxide barrier between the active device layers provides significant thermal protection to the bottom layer of devices during top-layer fabrication, the thermal processes of the latter  cannot be run at equilibrium. “One way of controlling the thermal budget is to use what we sometimes call the crème brûlée approach to only heat the very top surface while keeping the inside cool,” explained Vinet. “Everyone knows that you want a nice crispy top surface with cool custard beneath.” Using a laser with a short wavelength prevents penetration into lower layers such that essentially all of the energy is absorbed in the surface layer in a manner that can be considered as adiabatic.

Applied Materials has been a supplier-partner with Leti in developing M3D, and the company provided responses from executive technologists to queries from SST about the general industry trend to controlling short pulses of light for thermal processing. “Laser non-equilibrium heating is enabling technology for 3D devices,” affirmed Steve Moffatt, chief technology officer, Front End Products, Applied Materials. “The idea is to heat the top layer and not the layers below. To achieve very shallow adiabatic heating the toolset needs to ramp up in less than 100 nsec. In order to get strong absorption in the top surface, shorter wavelengths are useful, less than 800 nm. Laser non-equilibrium heating in this regime can be a critical process for building monolithic 3D structures for SOC and logic devices.”

Of course, with ultra-shallow junctions (USJ) and atomic-scale gate-stacks already in use for CMOS transistors at the 22nm-node, non-equilibrium thermal processing has already been used in leading fabs. “Gate dielectric, gate metal, and contact treatments are areas where we have seen non-equilibrium anneals slowly taking the place of conventional RTP,” clarified Abhilash Mayur, senior director, Front End Products, Applied Materials. “For approximate percentages, I would say about 25 percent of thermal processing for logic at the 22nm-node is non-equilibrium, and seen to be heading toward 50 percent at the 10nm-node or lower.”

Mayur further explained some of the trade-offs in working on the leading-edge of thermal processing for demanding HVM customers. Pulse-times are in the tens of nsec, with longer pulses tending to allow the heat to diffuse deeper and adversely alter the lower layers, and with shorter pulses tending to induce surface damage or ablation. “Our roadmap is to ensure flexibility in the pulse shape to tailor the heat flow to the specific application,” said Mayur.

Now that Qualcomm has endorsed CoolCube M3D as a preferred approach to CMOS:CMOS transistor stacking in the near-term, we may assume that R&D in novel unit-processes has mostly concluded. Presumably there are pilot lots of wafers now being run through commercial foundries to fine-tune M3D integration. With a roadmap for long-term heterogeneous integration that seems both low-cost and low-risk, M3D using non-equilibrium RTP will likely be an important way to integrate new functionalities into future ICs.

5nm Node Needs EUV for Economics

Thursday, January 29th, 2015


By Ed Korczynski, Sr. Technical Editor


At IEDM 2014 last month in San Francisco, Applied Materials sponsored an evening panel discussion on the theme of “How do we continue past 7nm?” Given that leading fabs are now ramping 14nm node processes, and exploring manufacturing options for the 10nm node, “past 7nm” means 5nm node processing. There are many device options possible, but cost-effective manufacturing at this scale will require Extreme Ultra-Violet (EUV) lithography to avoid the costs of quadruple-patterning.

Fig. 1: Panelists discuss future IC manufacturing and design possibilities in San Francisco on December 16, 2014. (Source: Pete Singer)

Figure 1 shows the panel being moderated by Professor Mark Rodwell of the University of California Santa Barbara, composed of the following industry experts:

  • Karim Arabi, Ph.D. – vice president, engineering, Qualcomm,
  • Michael Guillorn, Ph.D. – research staff member, IBM,
  • Witek Maszara, Ph.D. – distinguished member of technical staff, GLOBALFOUNDRIES,
  • Aaron Thean, Ph.D. – vice president, logic process technologies, imec, and
  • Satheesh Kuppurao, Ph.D. – vice president, front end products group, Applied Materials.

Arabi said that from the design perspective the overarching concern is to keep “innovating at the edge” of instantaneous and mobile processing. At the transistor level, the 10nm node process will be similar to that at the 14nm node, though perhaps with alternate channels. The 7nm node will be an inflection point with more innovation needed such as gate-all-around (GAA) nanowires in a horizontal array. By the 5nm node there’s no way to avoid tunnel FETs and III-V channels and possibly vertical nanowires, though self-heating issues could become very challenging. There’s no shortage of good ideas in the front end and lots of optimism that we’ll be able to make the transistors somehow, but the situation in the backend of on-chip metal interconnect is looking like it could become a bottleneck.

Guillorn extolled the virtues of embedded-memory to accelerate logic functions, as a great example of co-optimization at the chip level providing a real boost in performance at the system level. The infection at 7nm and beyond could lead to GAA Carbon Nano-Tube (CNT) as the minimum functional device. It’s limited to think about future devices only in terms of dimensional shrinks, since much of the performance improvement will come from new materials and new device and technology integration. In addition to concerns with interconnects, maintaining acceptable resistance in transistor contacts will be very difficult with reduced contact areas.

Maszara provided target numbers for a 5nm node technology to provide a 50% area shrink over 7nm:  gate pitch of 30nm, and interconnect level Metal 1 (M1) pitch of 20nm. To reach those targets, GLOBALFOUNDRIES’ cost models show that EUV with ~0.5 N.A. would be needed. Even if much of the lithography could use some manner of Directed Self-Assembly (DSA), EUV would still be needed for cut-masks and contacts. In terms of device performance, either finFET or nanowires could provide desired off current but the challenge then becomes how to get the on current for intended mobile applications? Alternative channels with high mobility materials could work but it remains to be seen how they will be integrated. A rough calculation of cost is the number of mask layers, and for 5nm node processing the cost/transistor could still go down if the industry has ideal EUV. Otherwise, the only affordable way to go may be stay at 7nm node specs but do transistor stacking.

Thein detailed why electrostatic scaling is a key factor. Parasitics will be extraordinary for any 5nm node devices due to the intrinsically higher number of surfaces and junctions within the same volume. Just the parasitic capacitances at 7nm are modeled as being 75% of the total capacitance of the chip. The device trend from planar to finFET to nanowires means proportionally increasing relative surface areas, which results in inherently greater sensitivity to surface-defects and interface-traps. Scaling to smaller structures may not help you if you loose most of the current and voltage in non-useful traps and defects, and that has already been seen in comparisons of III-V finFETs and nanowires. Also, 2D scaling of CMOS gates is not sustainable, and so one motivation for considering vertical transistors for logic at 5nm would be to allow for 20nm gates at 30nm pitch.

Kappurao reminded attendees that while there is still uncertainty regarding the device structures beyond 7nm, there is certainty in 4 trends for equipment processes the industry will need:

  1. everything is an interface requiring precision materials engineering,
  2. film depositions are either atomic-layer or selective films or even lattice-matched,
  3. pattern definition using dry selective-removal and directed self-assembly, and
  4. architecture in 3D means high aspect-ratio processing and non-equilibrium processing.

An example of non-equilibrium processing is single-wafer rapid-thermal-annealers (RTA) that today run for nanoseconds—providing the same or even better performance than equilibrium. Figure 2 shows that a cobalt-liner for copper lines along with a selective-cobalt cap provides a 10x improvement in electromigration compared to the previous process-of-record, which is an example of precision materials engineering solving scaling performance issues.

Fig. 2: ElectroMigration (EM) lifetimes for on-chip interconnects made with either conventional Cu or Cu lined and capped with Co, showing 10 times improvement with the latter. (Source: Applied Materials)

“We have to figure out how to control these materials,” reminded Kappurao. “At 5nm we’re talking about atomic precision, and we have to invent technologies that can control these things reliably in a manufacturable manner.” Whether it’s channel or contact or gate or interconnect, all the materials are going to change as we keep adding more functionality at smaller device sizes.

There is tremendous momentum in the industry behind density scaling, but when economic limits of 2D scaling are reached then designers will have to start working on 3D monolithic. It is likely that the industry will need even more integration of design and manufacturing, because it will be very challenging to keep the cost-per-function decreasing. After CMOS there are still many options for new devices to arrive in the form of spintronics or tunnel-FETs or quantum-dots.

However, Arabi reminded attendees as to why the industry has stayed with CMOS digital synchronous technology leading to design tools and a manufacturing roadmap in an ecosystem. “The industry hit a jackpot with CMOS digital. Let’s face it, we have not even been able to do asynchronous logic…even though people tried it for many years. My prediction is we’ll go as far as we can until we hit atomic limits.”

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